for AIChE-2026, #1

Zero-carbon hydrogen production by thermo-chemical water splitting. Abstract. Synergy of (1) New kind of catalysts. It is an reversible circular reaction (catalyst in wide sense), that is added to a target reaction to form a joint process. (2) Wind and solar energy can be in order of magnitude cheapened. For example, the water thermolysis at breakthrough lower temperature is estimated just below. (1) Catalyst is 0.5 * N2 + 1.5 * H2 = NH3 is joined with 0.365 mol of the water splitting, it gives a heat in electricity as a by-product and 0.365 mol of H2 at T > 785 Celsius, vs. conventional 2500 C, and consuming a heat of 142 kJ /0.365 = 390 kJ/mol minus sold electricity. Because all reagents are circular and so practically free, so Opex cost of the hydrogen is USD 38/ton H2 + USD 67 * 2 = 134 CAPEX, and totally USD 172 /ton H2. (2) Catalyst: CO2 + H2 = HCOOH - formic acid. Joint target reaction: HCOOH + 0.4 * (H2O = H2 + 0.5 O2) + CO2 + H2. dH = 32 + 0.4 * 242 = 128 kJ. dS = 214 + 0.4 * (131 + 102 - 180) = 234. dG = 128 - 234 * T < 0, and T > 274 C.

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