Al2O3 + 2 NH3 as a new kind of catalysts. Corrected.
Al2O3 + 2 NH3 as new kind of catalyst - Corrected.
David Judbarovski, systems engineering, principle inventor. judbarovski.blogspot.com, judbarovski@gmail.cvom
April 12, 2026
(1) Al2O3 + 2 NH3 = 2 AlN + 3 H2O. dH = 274 kJ, dS = 181 J /mol * K. Because all reagents here are circular, they are practically free (see reaction (2) for the water thermolysis). (2) (2 AlN + 3 H2O) + k * (H2O = H2 + O.5 O2) + (Al2O3 + 2 NH3), T > (k * 286 – 274) * 1000) / (k * 54 – 181). If k = 1.0, the reaction (2) is spontaneous at T <100 C. for k = 0.5, T > 720 C.. OPEX cost of the hydrogen product practically is equal to a cost of energy consumed. It is 286 kJ/mol = USD 286 * 1.1 / 2 = USD160/ton H2. If H2O-steam, the said cost is USD 133 /ton H2 References. 2021 Annual Meeting. (397e) Cheap Energy is a Key to Competitive Artificial Fuels. https://www.aiche.org/conferences-events
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