Hydrogen by USD 0.1/kg is possible. Disclosure


Super-cheap Hydrogen produced by Super-cheap Device and Electricity
Author: David Judbarovski, systems’ engineering, principle inventor, Israel
Linkedin (eng.), Facebook (rus.), judbarobski@gmail.com
My professional personal sites: https://judbarovski.blogspot.com since 2017 and

There are no technological problems to produce pure hydrogen, is down to USD 0.1/kg, if using my special reactor for thermolysis of pure water, and if using an extremely novel and cheap electric-generator. The said hydrogen can be delivered in its liquefied form, if to any far point of the world, doubling a cost up to USD 0.16-0.2/kg.


Here just below I intend to show and numerically evaluate a design of the above-mentioned reactor as an example among some other possible variants being suitable too.

It comprises two thin sheets of titanium nitride or titanium carbide and titanium core between them.  The said sandwich is immersed in the middle of a plastic container with clean water inside environment, while the outer walls of the said container is covered by thin film of silver.

Let the said sheets be thin, while the said core having a melting point of 1668 Centigrade is heated a little lower than a melting point of the said thin sheets having the melting point either 3140 Centigrade for titanium carbide or 2950 for titanium nitride, the both being not solvable in the water and doesn’t react with it.

The said titanium core being melted electrically, it is pumped through the said sandwich from a storage vessel and back, so the said water is heated at first being turn into steam, and then the water vapor splits near inner walls of the said sandwich into hydrogen as a product and into oxygen as a by-product or waste. The said water consume is compensated by adding the cold water.

The said water environment can be in enough volume, (e.g. 1 liter or so) to be heated lower than the water boiling point, so the container’s walls can be an ordinary plastic. 

Now below I show a numerical evaluation of such design parameters and economics intended for experts.

Let the electric power consume of such device be 300 kW. Silver film on outer walls of the container reflects 95%-99%, of the said sandwich thermal irradiation, goes back for the water splitting. Let the said sandwich walls are 0.5 mm each. TiC thermal conductivity is 0.068 W/ (cm* K), and for TiN it is 0.34, created insignificant fall from ~3000 C on the said walls.
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Further, 300 kW/(286 kJ/mol) = 1.05 mol/sec = 2.1 gram H2/sec = 2.1 * 31 = 65 ton/year, or 325 ton of hydrogen product for 5 years of CAPEX payback.

Really, the helpful heat transfer is convective one, it is used for water splitting and equal approximately to thermal irradiation, so the sandwich walls total area – S (m2) can be calculated approximately from 300,000 Watt  = 5.67 * ((3000 - 300)/100)^4 * S, so S = 0.1 m2 totally.

We can control a temperature fall at the said sandwich walls as 50 C or so. Thermal capacity of titanium is Cp =25, A = 47, and density 4.5, so liquid Ti rate through the said sandwich is 300 kW /(25/47) /50  = 5.6 kg/s being 5.6/4.5 = 1250 cm3/s being 1250cm3/(0.1 m2/6 walls of a cube)  = 7.5 cm/s through the sandwich. That titanium must be stored for reliable operation, e. g. even as big as 250 kg, being a lion share of CAPEX, because TiC and  TiN are relatively negligible share, so 250/(300kW * 8500 hrs/yr * 5 years of payback) = 0.0002 kg/kWh, so the CAPEX is practically free share added to a cost of electricity consumed for the water splitting, was earlier estimated by me in above-mentioned reference [1] as 0.2 USA cents per kWh, so  0.2 * 40 kWh/kgH2 + 20% = USD 0.1/kgH2, and USD 0.16-0.2/kgH2  after transportation for distance up to 10,000 km. Q.E.D.!

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